A facile method for the preparation of bishomopropargylic alcohols from acyl chlorides

dc.creator	Vásquez Céspedes, Suhelen
dc.creator	Cabezas Pizarro, Jorge A.
dc.date.accessioned	2023-03-16T19:44:55Z
dc.date.available	2023-03-16T19:44:55Z
dc.date.issued	2014
dc.description.abstract	Controlled dilithiation of propargyl bromide with two equivalents of n-butyllithium, in the presence of TMEDA, produces the operational equivalent of the dianion 1,3-dilithiopropyne. The latter reacts efficiently with acid chlorides to produce bishomopropargylic alcohols in a single step route and with high regioselectivity and moderate yields.	es_ES
dc.description.procedence	UCR::Vicerrectoría de Docencia::Ciencias Básicas::Facultad de Ciencias::Escuela de Química	es_ES
dc.description.sponsorship	Consejo Nacional de Rectores //CONARE/Costa Rica	es_ES
dc.identifier.citation	https://www.sciencedirect.com/science/article/pii/S0040403914002007	es_ES
dc.identifier.doi	10.1016/j.tetlet.2014.01.144
dc.identifier.issn	0040-4039
dc.identifier.uri	https://hdl.handle.net/10669/88344
dc.language.iso	eng	es_ES
dc.rights	acceso embargado
dc.source	Tetrahedron Letters, 55 (2014) 1894–1897	es_ES
dc.subject	QUÍMICA	es_ES
dc.subject	1,3-Dilithiopropyne	es_ES
dc.subject	Propargyl bromide lithiation	es_ES
dc.subject	Homopropargylation	es_ES
dc.subject	Homopropargyl alcohols	es_ES
dc.subject	Bishomopropargyl alcohols	es_ES
dc.title	A facile method for the preparation of bishomopropargylic alcohols from acyl chlorides	es_ES
dc.type	artículo original	es_ES

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