Ethyl 5-[(ethoxycarbonyl)oxy]-5,5-diphenylpent-2- ynoate
Loading...
Files
Date
Authors
Cabezas Pizarro, Jorge A.
Campos Fernández, Cristian Saúl
Journal Title
Journal ISSN
Volume Title
Publisher
Abstract
The title compound, C 22 H22 O 5, crystallizes with two molecules in the
asymmetric unit, one of which shows disorder of its ethyl acetate group over
two sets of sites in a 0.880 (2):0.120 (2) ratio. The C C distances in the two
molecules are almost the same [1.1939 (16) and 1.199 (2) A ̊ ], but the Csp3 C C angles differ somewhat [175.92 (12) and 172.53 (16)]. In the crystal,
several weak C—HO interactions are seen.
Description
Keywords
Química Cristalografía, QUÍMICA, homopropargyl alcohols, 1,3-dilithiopropyne, propargylation, alkynes
Citation
https://iucrdata.iucr.org/x/issues/2019/11/00/hb4323/index.html