Logo Kérwá
 

An Improved stereospecific synthesis of (Z,E)-tetradecadienal. Sex pheromone component of Stenoma cecropia

Loading...
Thumbnail Image

Date

Authors

Cabezas Pizarro, Jorge A.
Oehlschlager, Allan Cameron

Journal Title

Journal ISSN

Volume Title

Publisher

Abstract

(Z,E)-9, 11-Tetradecadienal, a sex pheromone component of Stenoma cecropia, has been synthesized in 7 steps and 61% overall yield. The synthesis utilized a palladium catalyzed coupling between 9-decynyl tert-butyldinethylsilyl ether and trans-1-iodo-butene, followed by reduction of triple bond of enyne with disiamylborane. Deprotection of silyl ether and oxidation afforded the desired aldehyde.

Description

Keywords

QUÍMICA, ANÁLISIS QUÍMICO, HORMONA, COMPUESTO QUÍMICO

Citation

Collections

Endorsement

Review

Supplemented By

Referenced By