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Direct functionalization of Mn12-(methacrylate) clusters on Si(100): surface characterization and electrochemical properties
(2016-09)
The reaction of H–terminated Si(100) with methacrylate–substituted manganese carboxylate clusters [Mn12O12{CH2C(CH3)COO}16(H2O)4], [Mn12–(methacrylate)] via hydrosilylation afforded Mn12–(methacrylate)−Si(100). The chemically ...
Neutral organic redox pairs based on sterically hindered hydroquinone/benzoquinone derivatives for dye-sensitized solar cells
(2018-06)
Substituted derivatives of hydroquinone/benzoquinone were studied as organic redox mediators in the electrolyte for dye-sensitized solar cells (DSSCs). Thus, di-tert-butylhydroquinone (DTHQ), thymohydroquinone (ThymHQ) and ...
Dye‐sensitized Devices: Photovoltaic and Photoelectrolytic Applications
(2018-11)
Dye‐sensitized approach along with stability and surface robustness in titanium dioxide (TiO2) against photocorrosion and degradation has been widely studied and applied in several important applications. This chapter ...
Synthesis and Crystal Structure of a Copper(II) Benzoate Complex Bearing a Bis-2,2′-Tetrahydrofuryl Peroxide Moiety
(2018-12)
Complex [Cu2(ben)4·2THF−(η1–O2)]∞ (2) (ben=C6H5CO2− benzoate; THF=tetrahydrofuran) was isolated when a solution of Cu2(ben)4·2THF (1) in THF upon natural sunlight irradiation yields crystals suitable for single-crystal ...
Bis(μ2-benzoato-κ2O,O′)bis(benzoato-κO)bis(ethanol-κO)bis(μ3-hydroxido)hexakis(μ-pyrazolato-κ2N,N′)hexacopper(II) ethanol disolvate
(2019)
Trinuclear copper–pyrazolate entities are present in various Cu-based enzymes and nanojar supramolecular arrangements. The reaction of copper(II) chloride with pyrazole (pzH) and sodium benzoate (benzNa) assisted by ...
μ2-Chlorido-chlorido(μ2-4-{[2-(diethylamino)ethyl]imino}pent-2-en-2-olato)bis(tetrahydrofuran-κO)cobalt(II)lithium
(2018)
The crystal structure of the title compound, [CoLi(C11H21N2O)Cl2(C4H8O)2], has monoclinic symmetry and comprises one heterometallic binuclear complex molecule in the asymmetric unit. The Co2+ cation is bonded to one oxygen ...
Crystal structure of (E)-2-(tert-butylamino)-4-(tertbutylimino)naphthalen-1(4H)-one
(2018)
The title compound, C18H24N2O, is the first example of a naphthoquinone imine derivative isolated in the 4-imine/2-amine tautomeric form having bulky alkyl substituents at the N atoms. The molecular conformation is stabilized ...
Experimental and theoretical studies of C–H⋯M interactions in palladium and platinum complexes derived from 1,2-bis-(2-hydroxymethylphenylthio)ethane
(2015-02)
The molecular structures of several related cis-[j2-SS-(L)MHal2] compounds 1, 1DMSO, 2, 2H2O,
3DMSO, 4 and 5 where L = HOCH2Ph-S-CH2-CH2-S-PhCH2OH, M = Pd or Pt, and Hal = Cl or Br or I, were analyzed by single crystal ...
Microwave assisted synthesis: A Mn/Ni reaction system affording Mn5Ni4, Mn2Ni2 and Mn7 complexes
(2013-11)
Following our interest in microwave assisted synthesis in coordination chemistry; we report here the results of the study of a mixed metal Mn/Ni system under common bench-top conditions and using the microwave reactor. ...
Síntesis y evaluación de complejos de cobre (I/II) con ligandos polipiridínicos como mediadores redox en celdas solares sensibilizadas con tintes
(2020)
En las celdas solares sensibilizadas con tintes (DSSCs), el mediador redox en el electrolito permite la transferencia de cargas al regenerar las moléculas del tinte durante su operación. Se sintetizaron y caracterizaron ...