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dc.creatorLedezma Gairaud, Marisol
dc.creatorPineda Cedeño, Leslie William
dc.creatorAromí, Guillem
dc.creatorSañudo, E. Carolina
dc.date.accessioned2020-02-28T21:11:36Z
dc.date.available2020-02-28T21:11:36Z
dc.date.issued2015
dc.identifier.citationhttps://www.sciencedirect.com/science/article/pii/S0020169315002947#!es_ES
dc.identifier.issn0020-1693
dc.identifier.urihttp://hdl.handle.net/10669/80665
dc.description.abstractMicrowave assisted synthesis and bench-top reactions are compared for Mn and Mn/Ni reaction systems with substituted salicylic acid (2-hydroxy-6-isopropyl-3-methylbenzoic-acid (SALOH2). When Mn salts are used, the microwave assisted synthesis and the bench-top reaction afford the same product: the new octanuclear Mn(II)/Mn(III) complex [Mn8O2(OMe)2Cl2(SALO)6(MeOH)4(H2O)2] (1). However, in a mixed metal Mn/Ni reaction the bench-top reaction results in the new heterometallic distorted cubane complexes [Pr2NH2][Mn2Ni2(OH)2(L1)2(SALO)2(SALOH)3] (where L1H = 3-dimethylamino-1-propanol), (2) and [Pr2NH2][Mn2Ni2(OH)(OMe)2(L1)(MeCN)(SALO)2(SALOH)3] (3). The crystal structure and magnetic properties of the prepared complexes are presented.es_ES
dc.description.sponsorshipSpanish Government/[CTQ2012-32247]//Españaes_ES
dc.description.sponsorshipUniversidad de Costa Rica/[115-B1-168]/UCR/Costa Ricaes_ES
dc.language.isoen_USes_ES
dc.sourceInorganica Chimica Acta, vol.434(1), pp.215-220es_ES
dc.subjectMicrowave assisted synthesises_ES
dc.subjectMagnetic propertieses_ES
dc.subjectHigh-nuclearity complexeses_ES
dc.titleSynthesis and characterization of new mixed-valent Mn(II)/Mn(III) and mixed metal Ni/Mn complexeses_ES
dc.typeinfo:eu-repo/semantics/articlees_ES
dc.identifier.doi10.1016/j.ica.2015.05.030
dc.description.procedenceUCR::Vicerrectoría de Investigación::Unidades de Investigación::Ciencias Básicas::Centro de Investigación en Electroquímica y Energía Química (CELEQ)es_ES
dc.description.procedenceUCR::Vicerrectoría de Docencia::Ciencias Básicas::Facultad de Ciencias::Escuela de Químicaes_ES
dc.identifier.codproyecto115-B1-168


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