Buscar
Mostrando ítems 1-10 de 156
Synthesis of 2-hydroxy-3-substituted naphthoquinones using the Heck reaction
(2007-06)
An efficient Heck coupling of 2-hydroxy-3-iodo-naphthoquinone with a series of electron-deficient alkenes in aqueous solution has been accomplished. The method is characterized by simple conditions and facile work-up to ...
Propargylation of Carbonyl Compounds: An Efficient Method for the Synthesis of Homopropargyl Alcohols
(1998)
Controlled dilithiation of allene, with two equivalents of n-butytlithium, produces the propargyl dianion 5. The latter couple efficiently with carbonyl compounds to produce homopropargyl alcohols in high yields.
Bile salts and derivatives: Rigid unconventional amphiphiles as dispersants, carriers and superstructure building blocks
(2015)
Steroidal surfactants like bile salts have a rigid amphiphilic structure significantly different from the typical head–tail one. As a result, these molecules show peculiar features in their self-assembly behavior and ...
Photoreactivity of Oil and Alcoholic Diterpenic Varnishes: Key Role of the Polymerization Process
(2020)
he conservation of artworks is a key issue in cultural heritage. The alterations of the varnish could be linked mainly to the photopolymerization of the natural resin. The photodegrada- tion of sandarac and rosin under ...
Concomitant prediction of environmental fate and toxicity of chemical compounds
(2020)
The environmental fate of many functional molecules that are produced on a large scale as precursors or as additives to specialty goods (plastics, fibers, construction materials, etc.), let alone those synthesized by the ...
Ethyl propionate: Synergistic kairomone for african palm weevil,Rhynchophorus phoenicis L. (Coleoptera: Curculionidae)
(1994-04)
Small trunk pieces of a freshly felled 10-year-old oil palm,Elaeis quineensis (Jacq.), were placed in a modified Nalgene desiccator, and volatiles captured for six days on Porapak Q. Gas chromatographic (GC) analysis of ...
Electrochemical biosensor for quantitative determination of fentanyl based on immobilized cytochrome c on multi-walled carbon nanotubes modified screen-printed carbon electrodes
(2022)
Fentanyl is a powerful synthetic opioid used to treat severe pain. New administration routes toward its illegal consumption
for recreational purposes pose a growing threat to public health, either due to misuse or abuse ...
Assessing the reactive surface area of soils and the association of soil organic carbon with natural oxide nanoparticles using ferrihydrite as proxy
(2020-09-09)
Assessment of the surface reactivity of natural metal-(hydr)oxide nanoparticles is necessary for predicting ion adsorption phenomena in soils using surface complexation modeling. Here, we describe how the equilibrium ...
Predation of the Rolled-Leaf Beetle Cephaloleia kressi García-Robledo (Coleoptera: Chrysomelidae: Cassidinae) by the Rove Beetle Phanolinus Sp. (Coleoptera: Staphylinidae: Xanthopygina) in a Montane Forest of Costa Rica
(2020-12-22)
The genus Cephaloleia Chevrolat includes 215 species, known as rolled-leaf beetles, all of which are restricted to the Neotropics (Garcı́a-Robledo et al. 2015; Staines and Garcı́a-Robledo 2014). These beetles complete their ...
Tetraaquabis(2,3-dihydro-1,4-benzodioxine-2-carboxylato)calcium(II)
(2020)
The acid–base reaction of 1,4-benzodioxane 2-carboxylic acid with calcium carbonate furnished the centrosymmetric title compound, [Ca(C9H7O4)2(H2O)4], in which the metal ion is octahedrally coordinated by two monodentate ...