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Surface area of ferrihydrite consistently related to primary surface charge, ion pair formation, and specific ion adsorption
(2020-01-20)
The specific surface area (SSA) of metal oxides is pivotal for scaling of surface phenomena. For ferrihydrite (Fh), the SSA can be assessed by probing the surface with ions that specifically adsorb (e.g. protons or phosphate). ...
Bioassay-guided isolation of anti-inflammatory O-sulfated withanolides from Acnistus arborescens (Solanaceae)
(2019)
Bioassay-guided fractionation of Acnistus arborescens (Solanaceae) organic extract afforded two anti-inflammatory withanolides: 2,3-Dihydro-3β-O-sulfate withacnistin (1) and 2,3-Dihydro-3β-O-sulfate withaferin A (2) showing ...
Crystal structure of (E)-2-(tert-butylamino)-4-(tertbutylimino)naphthalen-1(4H)-one
(2018)
The title compound, C18H24N2O, is the first example of a naphthoquinone imine derivative isolated in the 4-imine/2-amine tautomeric form having bulky alkyl substituents at the N atoms. The molecular conformation is stabilized ...
Critical Assessment of pH-Dependent Lipophilicity Profiles of Small Molecules: Which One Should We Use and In Which Cases?
(2023-10-03)
Lipophilicity is a physicochemical property with wide relevance in drug design, computational biology, food, environmental and medicinal chemistry. Lipophilicity is commonly expressed as the partition coefficient for neutral ...
Detection of the adsorption of water monolayers through the ion oscillation frequency in the magnesium oxide lattice by means of low energy electron diffraction
(2016-03)
We investigate the variation of the oscillation frequency of the Mg2+ and O2− ions in the magnesium oxide lattice due to the interactions of the surface with water monolayers by means of Low Energy Electron Diffraction. ...
Efficient syntheses of streptocarpone and (±)-a-dunnione
(2007)
An efficient divergent synthesis of both streptocarpone and racemic α-dunnione from lawsone are described. A one-pot, formal [3+2] cyclization to form a furanonaphthoquinone directly provided a common intermediate.
Synthesis of N-[3-(prop-1-yn-1-yl)phenyl] benzene sulfonamide and Determination of its Antibacterial Activity
(2019-07-25)
The synthesis of N-[3-(prop-1-yn-1-yl)phenyl] benzenesulfonamide was performed and its antibacterial activity against Staphylococcus aureus and Escherichia coli was determined. Minimalinhibitory concentrations (MIC) of ...
Una nueva ruta para la sintesis de la feromona sexual de la polilla de la papa, Scrobipalpopsis solanivora
(1996)
Acetato de (E)-3-dodecenilo, principal componente de feromona de Scrobipal-popsis solanivora, se preparó con un rendimiento total del 61 %. El precursor, 3-dodecin-1-ol, se preparó en el paso de un recipiente mediante la ...
Low CyaA expression and anti‐cooperative binding of cAMP to CRP frames the scope of the cognate regulon of Pseudomonas putida
(2021-03)
Although the soil bacterium Pseudomonas putida
KT2440 bears a bona fide adenylate cyclase gene
(cyaA), intracellular concentrations of 30,50-cyclic
adenosine monophosphate (cAMP) are barely detectable.
By using reporter ...
Análisis de residuos de plomo en repollo de Costa Rica
(1984)
Lead residues analysis in cabbage. Cabbage and soil samples from the main cabbage growing areas of Costa Rica were analyzed for lead residues. Lead residues result from the use of lead arseniate as an insecticide and ...