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Desarrollo de sensores electroquímicos para la determinación de drogas sintéticas en fluidos biológicos y muestras de incautación
(2023-07-09)
La cantidad de nuevas sustancias psicoactivas, popularmente conocidas con términos como: drogas emergentes, drogas de diseño, drogas sintéticas o drogas recreativas, aumenta en el mercado global de las drogas cada año. El ...
Bile salts and derivatives: Rigid unconventional amphiphiles as dispersants, carriers and superstructure building blocks
(2015)
Steroidal surfactants like bile salts have a rigid amphiphilic structure significantly different from the typical head–tail one. As a result, these molecules show peculiar features in their self-assembly behavior and ...
Electrochemical biosensor for quantitative determination of fentanyl based on immobilized cytochrome c on multi-walled carbon nanotubes modified screen-printed carbon electrodes
(2022)
Fentanyl is a powerful synthetic opioid used to treat severe pain. New administration routes toward its illegal consumption
for recreational purposes pose a growing threat to public health, either due to misuse or abuse ...
Tetraaquabis(2,3-dihydro-1,4-benzodioxine-2-carboxylato)calcium(II)
(2020)
The acid–base reaction of 1,4-benzodioxane 2-carboxylic acid with calcium carbonate furnished the centrosymmetric title compound, [Ca(C9H7O4)2(H2O)4], in which the metal ion is octahedrally coordinated by two monodentate ...
Operando tracking of oxidation-state changes by coupling electrochemistry with time-resolved X-ray absorption spectroscopy demonstrated for water oxidation by a cobalt-based catalysts film
(2021)
Transition metal oxides are promising electrocatalysts for water oxidation, i.e., the oxygen evolution reaction (OER), which is
critical in electrochemical production of non-fossil fuels. The involvement of oxidation state ...
Experimental and theoretical studies of C–H⋯M interactions in palladium and platinum complexes derived from 1,2-bis-(2-hydroxymethylphenylthio)ethane
(2015-02)
The molecular structures of several related cis-[j2-SS-(L)MHal2] compounds 1, 1DMSO, 2, 2H2O,
3DMSO, 4 and 5 where L = HOCH2Ph-S-CH2-CH2-S-PhCH2OH, M = Pd or Pt, and Hal = Cl or Br or I, were analyzed by single crystal ...
Tropical Atmospheric Corrosion of Galvanized Steel, in a light urban atmosphere in the San José Valley of Costa Rica
Corrosión atmosférica tropical de Hierro Galvanizado en una atmósfera urbana leve, en el Valle de San José de Costa Rica
(2022)
Costa Rica imports most of the metallic materials it uses. In construction, Galvanized Steel (GS) is one of the most used elements in urban areas, where atmospheric corrosion is the main problem of its environmental ...
Synthesis and Crystal Structure of a Copper(II) Benzoate Complex Bearing a Bis-2,2′-Tetrahydrofuryl Peroxide Moiety
(2018-12)
Complex [Cu2(ben)4·2THF−(η1–O2)]∞ (2) (ben=C6H5CO2− benzoate; THF=tetrahydrofuran) was isolated when a solution of Cu2(ben)4·2THF (1) in THF upon natural sunlight irradiation yields crystals suitable for single-crystal ...
Rapid Determination of the ‘Legal Highs’ 4-MMC and 4-MEC by Spectroelectrochemistry: Simultaneous Cyclic Voltammetry and In Situ Surface-Enhanced Raman Spectroscopy
(2021-12-31)
The synthetic cathinones mephedrone (4-MMC) and 4-methylethcathinone (4-MEC) are
two designer drugs that represent the rise and fall effect of this drug category within the stimulants
market and are still available in ...
Direct functionalization of Mn12-(methacrylate) clusters on Si(100): surface characterization and electrochemical properties
(2016-09)
The reaction of H–terminated Si(100) with methacrylate–substituted manganese carboxylate clusters [Mn12O12{CH2C(CH3)COO}16(H2O)4], [Mn12–(methacrylate)] via hydrosilylation afforded Mn12–(methacrylate)−Si(100). The chemically ...