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A New Method for the Preparation of 1-Ethynyl Ethers
(1994)
During our study of the stannylcupration of acetylenic
ethers we required [2-13C]-1 for mechanistic studies.
Existing methods for the synthesis of acetylenic ethers
involve dehydrohalogenation of 2-halo, ...
An improved stereospecific synthesis of (Z,E)-9, 11, 13-Tetradecatrienal. Sex pheromone component of Stenoma cecropia
(2000)
(Z,E)-9,11,13-tetradecatrienal, a pheromone component of Stenoma cecropia, was prepared in 61% overall yield from 1-nonyne. The synthesis involved two palladium-catalyzed cros-couplings to afford a 1,3-dien5-yne, which was ...
Stereospecific Synthesis of (E, Z)- and (Z, Z)-Hexadeca-10,12-dienal. Sex Pheromone Components of Diaphania hyalinata
(1998)
Isomeric (E,Z)- and (Z,Z)-hexadeca-10,12-dienal were prepared, stereospecifically, in 51% and 43% overall yields from dec-1-yne.
An Improved stereospecific synthesis of (Z,E)-tetradecadienal. Sex pheromone component of Stenoma cecropia
(1998)
(Z,E)-9, 11-Tetradecadienal, a sex pheromone component of Stenoma cecropia, has been synthesized in 7 steps and 61% overall yield. The synthesis utilized a palladium catalyzed coupling between 9-decynyl tert-butyldinethylsilyl ...