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Experimental and theoretical studies of C–H⋯M interactions in palladium and platinum complexes derived from 1,2-bis-(2-hydroxymethylphenylthio)ethane
(2015-02)
The molecular structures of several related cis-[j2-SS-(L)MHal2] compounds 1, 1DMSO, 2, 2H2O,
3DMSO, 4 and 5 where L = HOCH2Ph-S-CH2-CH2-S-PhCH2OH, M = Pd or Pt, and Hal = Cl or Br or I, were analyzed by single crystal ...
Synthesis, structure and spectroscopic characterization of Ni(II), Co(II), Cu(II) and Zn(II) complexes with saccharinate and pyrazole
(2007-09)
Four mononuclear mixed-ligand complexes of Co(II), Ni(II), Cu(II) and Zn(II), with saccharin (sac) and pyrazole (Hpz) were synthesized and characterized on the basis of elemental analysis, FT-IR spectroscopy, magnetic ...
Microwave assisted synthesis: A Mn/Ni reaction system affording Mn5Ni4, Mn2Ni2 and Mn7 complexes
(2013-11)
Following our interest in microwave assisted synthesis in coordination chemistry; we report here the results of the study of a mixed metal Mn/Ni system under common bench-top conditions and using the microwave reactor. ...
Bis(μ2-benzoato-κ2O,O′)bis(benzoato-κO)bis(ethanol-κO)bis(μ3-hydroxido)hexakis(μ-pyrazolato-κ2N,N′)hexacopper(II) ethanol disolvate
(2019)
Trinuclear copper–pyrazolate entities are present in various Cu-based enzymes and nanojar supramolecular arrangements. The reaction of copper(II) chloride with pyrazole (pzH) and sodium benzoate (benzNa) assisted by ...
1,3-Bis{[(2,6-dimethylphenyl)sulfanyl]methyl}benzene
(2019)
The structure of the title compound, C24H26S2, an example of a pincer ligand with an SCS-chelation motif, illustrates the steric effects of the methyl groups in the thiophenyl rings at the 2- and 6-positions, forcing a ...
Crystal structures and biological activity of 1,1,4-triphenyl-substituted 1,3-enyne compounds
(2019)
1,3-Enyne structural motifs are versatile building blocks in organic synthesis and
occur widely in various natural products with many of them being highly active
as cytotoxic macrolides and antitumour antibiotics. This ...
Co-adsorbing effect of bile acids containing bulky amide groups at 3β-position on the photovoltaic performance in dye-sensitized solar cells
(2019)
Co-adsorbing molecules attain certain control in the surrounding of the dyes leading to enhanced efficiencies
mainly by affecting the recombination of the photogenerated electrons and aggregation of dyes. Bile acids ...
1-Nitro-4-(1-propyn-1-yl)benzene
(2019)
The title compound, C9H7NO2, was prepared by alkynylation of 4-iodonitrobenzene with 1,3-dilithiopropyne in the presence of 1 equivalent of CuI and catalytic amounts of Pd(PPh3)2Cl2. The complete molecule is generated ...
Synthesis and characterization of new mixed-valent Mn(II)/Mn(III) and mixed metal Ni/Mn complexes
(2015)
Microwave assisted synthesis and bench-top reactions are compared for Mn and Mn/Ni reaction systems with substituted salicylic acid (2-hydroxy-6-isopropyl-3-methylbenzoic-acid (SALOH2). When Mn salts are used, the microwave ...
Tetraaquabis(2,3-dihydro-1,4-benzodioxine-2-carboxylato)calcium(II)
(2020)
The acid–base reaction of 1,4-benzodioxane 2-carboxylic acid with calcium carbonate furnished the centrosymmetric title compound, [Ca(C9H7O4)2(H2O)4], in which the metal ion is octahedrally coordinated by two monodentate ...