A new method for the synthesis of 1,5-diynes, from the reaction of 1,3-dilithiopropyne and propargyl chlorides, was developed. This new methodology was used to prepare (4E,6Z,10Z)-4,6,10-hexadecatrien-1-ol, one of the ...

El siguiente documento es parte de un experimento científico que se titula “Propargylation of Alkyl Halides: (E)-6,10-dimethyl-5,9-undecadien-1-yne and (E)-7,11-dimethyl-6,10-dodecadien-2-yn-1-ol”. El mismo fue realizado ...

The title compound, C 22 H22 O 5, crystallizes with two molecules in the asymmetric unit, one of which shows disorder of its ethyl acetate group over two sets of sites in a 0.880 (2):0.120 (2) ratio. The C C distances ...

During our study of the stannylcupration of acetylenic ethers we required [2-13C]-1 for mechanistic studies. Existing methods for the synthesis of acetylenic ethers involve dehydrohalogenation of 2-halo, ...

From the leaves of Tabernaemontana arborea Rose (Apocynaceae) the triterpenoid lupeyl acetate and the indole alkaloids voacangine, 19 epivoacristine, vobasine and 19R-hydroxiconopharingine have been isolated and identified ...

(Z,E)-9, 11-Tetradecadienal, a sex pheromone component of Stenoma cecropia, has been synthesized in 7 steps and 61% overall yield. The synthesis utilized a palladium catalyzed coupling between 9-decynyl tert-butyldinethylsilyl ...

Sequential treatment of 2,3-dichloropropene with magnesium and n-BuLi generated the equivalent of 1,3- dilithiopropyne, which adds regiospecifically to aldehydes and ketones to produce homopropargyl alcohols. The ...

Several aromatic homopropargyl alcohols, and derivatives were prepared by one-pot reaction of 1,3-dilithiopropyne (or its equivalent) with aldehydes and ketones. The antibacterial activity, of alcohols ...

Jacaranone and several novel ester side chain derivatives have been synthesized and tested for antibacterial activity. The syntheses of these compounds involved the convenient lithium enolate ester adition to p-benzoquinone. ...

Acetato de (E)-3-dodecenilo, principal componente de feromona de Scrobipal-popsis solanivora, se preparó con un rendimiento total del 61 %. El precursor, 3-dodecin-1-ol, se preparó en el paso de un recipiente mediante la ...