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Microwave assisted synthesis: A Mn/Ni reaction system affording Mn5Ni4, Mn2Ni2 and Mn7 complexes
dc.creator | Ledezma Gairaud, Marisol | |
dc.creator | Pineda Cedeño, Leslie William | |
dc.creator | Aromí, Guillem | |
dc.creator | Sañudo, E. Carolina | |
dc.date.accessioned | 2018-12-20T15:43:57Z | |
dc.date.available | 2018-12-20T15:43:57Z | |
dc.date.issued | 2013-11 | |
dc.identifier.citation | https://www.sciencedirect.com/science/article/pii/S0277538713001113?via%3Dihub#! | |
dc.identifier.issn | 0277-5387 | |
dc.identifier.uri | https://hdl.handle.net/10669/76361 | |
dc.description.abstract | Following our interest in microwave assisted synthesis in coordination chemistry; we report here the results of the study of a mixed metal Mn/Ni system under common bench-top conditions and using the microwave reactor. Using bench-top, the mixed metal Mn/Ni complex Mn5Ni4(OH)4(C5H12NO)4(SALOH)6(SALO)4] (complex 1) is obtained while the microwave reactor affords a Mn7 complex, [Mn7(OH)3(C5H12NO)2(C5H13NO)(SALO)6(SALOH)3] complex 2, where the Ni(II) has not been incorporated or a Mn2Ni2 cubane, [Pr2NH2][Mn2Ni2(OH)2(C5H12NO)2(SALO)3(SALOH)2] complex 3. Graphical abstract Following our interest in microwave assisted synthesis in coordination chemistry; we report here the results of the study of a mixed metal Mn/Ni system under common bench-top conditions and using the microwave reactor. Using bench-top, the mixed metal Mn/Ni complex [Mn5Ni4(OH)4(C5H12NO)4(SALOH)6(SALO)4] (complex 1) is obtained while the microwave reactor affords a Mn7 complex, [Mn7(OH)3(C5H12NO)2(C5H13NO)(SALO)6(SALOH)3] complex 2, where the Ni(II) has not been incorporated or a Mn2Ni2 cubane, [Pr2NH2][Mn2Ni2(OH)2(C5H12NO)2(SALO)3(SALOH)2] complex 3. | es_ES |
dc.description.sponsorship | Universidad de Costa Rica/[115-B1-168]/UCR/Costa Rica | es_ES |
dc.description.sponsorship | Gobierno español/[CTQ2009-06959]//España | es_ES |
dc.language.iso | en_US | es_ES |
dc.relation.ispartof | ||
dc.source | Polyhedron, vol. 64(12), pp. 45-51 | es_ES |
dc.subject | Magnetism | es_ES |
dc.subject | Microwave assisted synthesis | es_ES |
dc.subject | Coordination chemistry | es_ES |
dc.subject | George Christou 60th birthday special issue | es_ES |
dc.subject | 543.085 82 Espectroscopia de microondas | es_ES |
dc.title | Microwave assisted synthesis: A Mn/Ni reaction system affording Mn5Ni4, Mn2Ni2 and Mn7 complexes | es_ES |
dc.type | artículo original | |
dc.date.updated | 2018-12-13T20:24:16Z | |
dc.identifier.doi | 10.1016/j.poly.2013.02.018 | |
dc.description.procedence | UCR::Vicerrectoría de Investigación::Unidades de Investigación::Ciencias Básicas::Centro de Investigación en Electroquímica y Energía Química (CELEQ) | es_ES |
dc.description.procedence | UCR::Vicerrectoría de Docencia::Ciencias Básicas::Facultad de Ciencias::Escuela de Química | es_ES |
dc.identifier.codproyecto | 115-B1-168 |
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