Now showing items 1-20 of 360
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1,1-Diphenyl-4-(thiophen-2-yl)but-3-yn-1-ol
(2018-11)The asymmetric unit of the title homopropargyl alcohol, C20H16OS, contains two independent molecules comprising a hydroxy group, a 3-(2-thiophenyl)- propargylic moiety and two aromatic rings linked to a central carbon atom. ... -
1,3-Bis{[(2,6-dimethylphenyl)sulfanyl]methyl}benzene
(2019)The structure of the title compound, C24H26S2, an example of a pincer ligand with an SCS-chelation motif, illustrates the steric effects of the methyl groups in the thiophenyl rings at the 2- and 6-positions, forcing a ... -
1-Nitro-4-(1-propyn-1-yl)benzene
(2019)The title compound, C9H7NO2, was prepared by alkynylation of 4-iodonitrobenzene with 1,3-dilithiopropyne in the presence of 1 equivalent of CuI and catalytic amounts of Pd(PPh3)2Cl2. The complete molecule is generated ... -
(1S,3R)-N-{(3S,10S,12S,13R,17R)-12-Hydroxy-17- [(R)-5-hydroxypentan-2-yl]-10,13-dimethylhexa- decahydro-1H-cyclopenta[a]phenanthren-3-yl}- adamantane-1-carboxamide 0.25-hydrate
(2022-10-12)The title compound, C 35H 57 NO 3 0.25H 2O, was synthesized from deoxycholic acid followed by a protection, a Mitsonobu substitution, a Staudinger reduction, formation of an amide and final reduction in the lateral chain. ... -
5,5-Diphenyl-cis-penta-2,4-dienoic acid
(2019)In the title compound, C17H14O2, the dihedral angle between the phenyl rings is 76.52 (7)°. In the crystal, pairwise O—H⋯O hydrogen bonds link the molecules into carboxylic acid inversion dimers. -
A Chronoamperometric Screen Printed Carbon Biosensor Based on Alkaline Phosphatase Inhibition for W(VI) Determination in Water, Using 2-Phospho-l-Ascorbic Acid Trisodium Salt as a Substrate
(2015)This paper presents a chronoamperometric method to determine tungsten in water using screen-printed carbon electrodes modified with gold nanoparticles and cross linked alkaline phosphatase immobilized in the working ... -
A facile method for the preparation of bishomopropargylic alcohols from acyl chlorides
(2014)Controlled dilithiation of propargyl bromide with two equivalents of n-butyllithium, in the presence of TMEDA, produces the operational equivalent of the dianion 1,3-dilithiopropyne. The latter reacts efficiently with ... -
A Facile Method for the Titration of Organolithium Reagents using Naphtylamine or Naphtylmethylamine as Indicators
(2019)A simple method for the titration of alkyllithiums with sec-butanol, using naphtylamine or naphtylmethylamine as color indicator, is reported. Both amines gave sharp-end points, easily determined by color changes from ... -
A Metabolic Widget Adjusts the Phosphoenolpyruvate-Dependent Fructose Influx in Pseudomonas putida
(2016)Fructose uptake in the soil bacterium Pseudomonas putida occurs through a canonical phosphoenolpyruvate (PEP)-dependent sugar transport system (PTSFru). The logic of the genetic circuit that rules its functioning is puzzling: ... -
A new and efficient synthesis of (3E,8Z,11Z)-tetradeca-3,8,11-trienyl acetate, the major sex pheromone component of the tomato leafminer Tuta absoluta
(2018)An efficient synthesis of (3E,8Z,11Z)-tetradeca-3,8,11-trienyl acetate, the major sex pheromone component of the tomato leafminer moth, Tuta absoluta, was accomplished. The synthesis started with but-3-yn-1-ol and gave an ... -
A new method for the preparation of 1,3-dilithiopropyne: an efficient synthesis of homopropargyl alcohols
(2001)Controlled dilithiation of propargyl bromide with two equivalents of n-butyllithium, in the presence of TMEDA, produces the operational equivalent of the dianion 1,3-dilithiopropyne. The latter reacts efficiently with ... -
A New Method for the Preparation of 1,5-Diynes. Synthesis of (4E,6Z,10Z)-4,6,10-Hexadecatrien-1-ol, the Pheromone Component of the Cocoa Pod Borer Moth Conopomorpha cramerella
(2004)A new method for the synthesis of 1,5-diynes, from the reaction of 1,3-dilithiopropyne and propargyl chlorides, was developed. This new methodology was used to prepare (4E,6Z,10Z)-4,6,10-hexadecatrien-1-ol, one of the ... -
A New Method for the Preparation of 1-Ethynyl Ethers
(1994)During our study of the stannylcupration of acetylenic ethers we required [2-13C]-1 for mechanistic studies. Existing methods for the synthesis of acetylenic ethers involve dehydrohalogenation of 2-halo, ... -
A new methodology for the synthesis of δ-substituted α,β-unsaturated δ-lactones
(2020)A new protocol for the synthesis of δ-substituted-α,β-unsaturated δ-lactones was developed. Selective reaction of 1,3-dilithiopropyne with ketones, followed by addition of ethyl chloroformate formed ethyl 5-[(ethoxycarbo ... -
Aceptación de un jugo de mora endulzado con estevia en contraste con otros edulcorantes
(2017)El objetivo de la presente investigación fue desarrollar un jugo de mora (Rubus adenotrichus), endulzado con esteviolglucósidos (glucósidos obtenidos a partir de las hojas de Stevia rebaudina Bertoni) como una bebida ... -
Adipostatins E-J, new potent antimicrobials identified as inhibitors of coenzyme-A biosynthesis
(2020-01)Phosphopantetheine is a key structural element in biological acyl transfer reactions found embedded within coenzyme A (CoA). Phosphopantothenoylcysteine synthetase (PPCS) is responsible for installing a cysteamine group ... -
Aggregation Pheromone of Coconut Rhinoceros Beetle, Oryctes rhinoceros (L.) (Coleoptera: Scarabaeidae)
(1995-10)Male coconut rhinoceros beetles,Oryctes rhinoceros (L.), produce three sex-specific compounds, ethyl 4-methyloctanoate, ethyl 4-methylheptanoate, and 4-methyloctanoic acid, the first of which is an aggregation pheromone. ... -
Aggregation Pheromone of Palm Weevil, Dynamis borassi
(1997)4-Methyl-5-nonanol (1) is the male-produced aggregation pheromone of the palm weevil, Dynamis borassi (F.) from Colombia. The pheromone was identified by coupled gas chromatographic–electroantennographic detection (GC-EAD) ... -
Aggregation pheromone of palmetto weevil, Rhynchophorus cruentatus (F.) (Coleoptera: Curculionidae)
(1994)5-Methyl-4-octanol is the major aggregation pheromone of the palmetto weevil,Rhynchophorus cruentatus (F.). The pheromone (cruentol) was identified by coupled gas chromatographic-electroantennographic (GC-EAD) analysis of ... -
Aggregation Pheromone of the African Rhinoceros Beetle, Oryctes monoceros (Olivier) (Coleoptera: Scarabaeidae)
(1994)Coleoptera, Oryctes monoceros, African Rhinoceros Beetle, Aggregation Pheromone, Ethyl 4-M ethyloctanoate Ethyl 4-m ethyloctanoate is a male-produced aggregation pheromone of the African rhinoceros beetle, Oryctes monoceros ...